Abstract

We present a 13 year (2002-2015) semimonthly time series of the partial pressure of CO₂ in surface water (pCO₂surf) and other carbonate system parameters from the Drake Passage. This record shows a clear increase in the magnitude of the sea-air pCO₂ gradient, indicating strengthening of the CO₂ s... Show moreWe present a 13 year (2002-2015) semimonthly time series of the partial pressure of CO₂ in surface water (pCO₂surf) and other carbonate system parameters from the Drake Passage. This record shows a clear increase in the magnitude of the sea-air pCO₂ gradient, indicating strengthening of the CO₂ sink in agreement with recent large-scale analyses of the world oceans. The rate of increase in pCO₂surf north of the Antarctic Polar Front (APF) is similar to the atmospheric pCO₂ (pCO₂atm) trend, whereas the pCO₂surf increase south of the APF is slower than the pCO₂atm trend. The high-frequency surface observations indicate that an absence of a winter increase in total CO₂ (TCO₂) and cooling summer sea surface temperatures are largely responsible for increasing CO₂ uptake south of the APF. Muted winter trends in surface TCO₂ also provide temporary stability to the carbonate system that is already close to undersaturation with respect to aragonite. Show less